Suspect your ancestor Valentine Rinehart was the brother of Johan Georg and Johann Peter Rinehart, who came to this country from Germany and first settled in present day Lehigh Co., PA. That "Valentin" (as I found it spelled in early records) did indeed have a wife named Anna Barbara. On the negative side, I am only aware that they had three children: Mary Elisabeth, Valentin Jr., and Elisabeth Barbara, but none named George. This, of course, doesn't rule out the possibility they had other children, of whom one they named George. When you consider how large families more often were in Colonial America, it seems very likely that they did.
While I have done little research on Valentine, I have been extremely interested, and done a bit more research on his brother, Johan George, whose first son was named Abraham. While I have--so far--been unable to link my own ancestor to that Abraham, I have traced my own ancestor, Abraham Rinehart, from Manchester, Carroll Co., MD where George, his first son, was born about the same time that the other Abraham disappeared from Lehigh County.
What particularly fascinates me about your inquiry, is the reference you made to Valentine's having moved to Frederick County, VA. You perhaps already know that Hampshire County, WV was a part of Frederick County until it broke off sometime in the mid-1700's. Add to that the fact that in the mid-1780's, my own ancestor settled in the Eastern part of Hampshire County, not too far from the border shared with Frederick County.
But let me get back to Valentine and his brothers. If you think we are on the right track, it wouldn't be any trouble at all, to locate the mother's name for you. Meanwhile I can tell you that after their the death of their father died the three, the brothers were brought to this country by their mother, who by then had remarried.
Please feel free to let me know if you want the names.
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