Alfred's name should show up on Kentucky 1850 census with family. Payton and Peyton were commonly interchanged. The earliest confirmed information I have on Thomas was a marriage in Macon Co., MO to Nancy ? in 1856 (LDS records). Next was 1860 census in Macon Co., Mo. with first son Ambrosian, last name spelled Peyton. Nancy died after second son's birth and Thomas' name was spelled Payton thereafter. Sorry I cannot be of more help.
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