You can find him and his family mis-transcribed as "SHARMAN" in the 1851 census at http://automatedgenealogy.com/censusnb51/
Unfortunately there is no sin James listed with the family.
He is likely the son who was b. 1837 and died 1910...
Index to County Death Registers
Name Sherman, Valentine
Date of Death -04-29 (Y-M-D)
Residence St. David
County of Residence CHARLOTTE
Place of Death Tower Hill
County of Death CHARLOTTE
Place of Birth St. David
County of Birth CHARLOTTE
Reference C1d , Page 50, Line 11
Hope this helps,
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